Investigations into fuel reactivity using spray ignition experiments

Authors
Tekawade, Aniket
ORCID
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Other Contributors
Oehlschlaeger, Matthew A.
Chung, Aram
Borca-Tasçiuc, Theodorian
Plawsky, Joel L., 1957-
Issue Date
2017-08
Keywords
Mechanical engineering
Degree
PhD
Terms of Use
This electronic version is a licensed copy owned by Rensselaer Polytechnic Institute, Troy, NY. Copyright of original work retained by author.
Full Citation
Abstract
Experiments on aromatic compounds comprised of ignition delay measurements on blends of alkylbenzenes in n-alkanes and pure forms of two large alkylbenzenes (n-octylbenzene and n-decylbenzene). The DCN measurements for alkylbenzene and n-alkane blends decreased nonlinearly with increasing alkylbenzene content. A model was proposed to that accounts for this non-linearity by considering an apparent reaction rate order for the blended components. Comparisons of these blends with the large alkylbenzenes having identical proportions of aromatic carbons revealed that there is a synergistic effect of an attached benzyl group on the reactivity of the alkylbenzene. Hence, we conclude that blends of alkylbenznes in n-alkanes are not ideal surrogates to model the low-temperature reactivity of large alkylbenzenes.
Description
August 2017
School of Engineering
Department
Dept. of Mechanical, Aerospace, and Nuclear Engineering
Publisher
Rensselaer Polytechnic Institute, Troy, NY
Relationships
Rensselaer Theses and Dissertations Online Collection
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