Browsing RPI Theses Online (Complete) by Author "Palermo, Edmund"
Now showing items 1-17 of 17
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Characterization of intracortical microelectrode coatings to mitigate scarring and neurodegeneration in vivo
Ziemba, Alexis (Rensselaer Polytechnic Institute, Troy, NY, 2020-05)Pilot studies assessing the compatibility of the coatings revealed the hypothermic coating was toxic while PCPC coating was deemed suitable for future testing. The uniformity was assessed using scanning and confocal ... -
Characterizing Creatinine MIP Functionality Using Spectroscopy Techniques
Hovan, Bradley (Rensselaer Polytechnic Institute, Troy, NY, 2021-12)The availability and timely use of novel diagnostic tools often benefits the prognosis and progression of many common diseases, including chronic and acute kidney disease, through better allotment of scarce treatment ... -
Controlled degradation of bioresorbable polymers via external stimuli
Ehlers, Andrew (Rensselaer Polytechnic Institute, Troy, NY, 2016-12)Weight loss measurements proved to be the most effective method of tracking the extent of degradation in PCL films. Differential Scanning Calorimetry and Raman Spectroscopy proved to be inefficient in tracking or characterizing ... -
Controlling the properties and degradation kinetics of polyprodrug films
Falcone, Phillip (Rensselaer Polytechnic Institute, Troy, NY, 2020-05)The intent of this project is to characterize the properties and the kinetics of release of polyprodrugs made from estradiol and curcumin to develop biomaterials to be used with neuroprotective applications. For both ... -
Depth of cure effects on structure-property relationships of 3d printed polymer materials using stereolithography
Smallwood, Anna M. C. (Rensselaer Polytechnic Institute, Troy, NY, 2020-12)In Chapter 3, the effect of type and concentration of resin additive on photopolymerization kinetics is examined via RT-FTIR ATR. Factors such as network conversion and relative concentration of remaining double bonds ... -
Enhancing drug delivery from electrospun fiber scaffolds for neural tissue engineering
D'Amato, Anthony R. (Rensselaer Polytechnic Institute, Troy, NY, 2018-12)The final aim in this study details the creation of an entirely new polymer that is made out of E2. With the help of Dr. Palermo’s lab, I synthesized a new, slowly-degrading E2 and polyethylene glycol (PEG) copolymer (PPEAP) ... -
Ion-conducting polymers via acid-catalyzed polyhydroxyalkylation for electrochemical devices
Walgama, Ramali Chandula (Rensselaer Polytechnic Institute, Troy, NY, 2021-12)The dependency of modern-day human life on synthetic polymers is becoming increasingly evident. At present, polymers are used in a broad spectrum of applications, ranging from commodity polymers in everyday plastics, to ... -
Modeling interfaces in polymer nanodielectrics
Shandilya, Abhishek (Rensselaer Polytechnic Institute, Troy, NY, 2021-12)Ab initio design of polymer nanocomposite materials for high breakdown strength requires prediction of trap states at the polymer–filler interface. Systematic first-principles calculations of realistic interfaces can be ... -
Molecular dynamics simulations on polymeric materials
Deng, Binghui (Rensselaer Polytechnic Institute, Troy, NY, 2017-12)In the comparison of chain-growth polymerization in solution versus on surface, we found that surface-initiated polymer chains exhibited a markedly broader distribution of chain lengths and slower chain growth kinetics as ... -
Processing-structure-property relationships for polymer nanodielectrics
Prasad, Aditya Shanker (Rensselaer Polytechnic Institute, Troy, NY, 2019-05)The prepared nanocomposites were also characterized by dielectric spectroscopy and dielectric breakdown strength measurements. As the prepared nanocomposites showed a variation in dispersion state, at the same nanoparticle ... -
Soft lithographic printing of mesoscale periodic structures
Deagen, Michael Edward (Rensselaer Polytechnic Institute, Troy, NY, 2018-12)Wetting regimes for residual-layer-free filling provide a guide to materials selection and design for multi-layer transfer molding, and the anisotropic dewetting behavior provided insights into the process for achieving ... -
Spirothiopyran based super-resolution interference lithography
Vijayamohanan, Harikrishnan (Rensselaer Polytechnic Institute, Troy, NY, 2019-08)In this thesis, we develop a new super-resolution writing system with the desired low light thresholds for parallel nanopatterning by combining the reversibly saturable isomerization of photochromic spirothiopyran with the ... -
Structural (im)perfection in antibacterial oligomers
Zhou, Zhe (Rensselaer Polytechnic Institute, Troy, NY, 2020-05)In this dissertation, we designed a fully abiotic way to synthesize discrete unimolecular weight polyolefins by using a molecular template. We synthesized discrete and unimolecular oligo(thiophene)s template with alternating ... -
Structure-activity relationships in self-immolative and photodynamic antibacterial polymers
Ergene, Cansu (Rensselaer Polytechnic Institute, Troy, NY, 2019-05)We also developed silyl ether-capped PBE gels containing cationic or PEG units in side chains using PEG thiol crosslinkers via photoactivated thiol-ene click reaction. These gels maintained the self-immolation ability of ... -
Structure-property relationships in poly(pro-17-estradiol) materials and the effect on in vitro degradation kinetics
Hsu, Alexander (Rensselaer Polytechnic Institute, Troy, NY, 2021-08)Due to the refractory nature of the central nervous system (CNS), injuries such as spinal cord injury (SCI) trigger a complex injury cascade. Currently, no effective therapeutics exist to reverse the outcomes of progressive ... -
Study of polymer nanocomposites with chemically heterogeneous interfaces
Gong, Chen (Rensselaer Polytechnic Institute, Troy, NY, 2021-05)In bilayer thin films, PEO was always used as the second polymer layer, mimicking the matrix polymer in the 3-dimensional bulk nanocomposites. Three different polymers were used as the first polymer layer (the layer ... -
The impact of surface modification on magneto-functional iron oxide – polyethylene oxide nanocomposites
Weiblen, Donovan George, III (Rensselaer Polytechnic Institute, Troy, NY, 2022-08)Remote triggering of smart materials such as shape memory polymers and nanocomposites for drug delivery are research areas of continued interest for magneto-functional nanocomposites. Magnetically susceptible nanoparticles ...