Author
Linhardt, Robert J.; Murr, B.L.
Other Contributors
Date Issued
1979
Subject
Biology; Chemistry and chemical biology; Chemical and biological engineering; Biomedical engineering
Degree
Terms of Use
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Full Citation
Mechanism of Decomposition for Diacyl Peroxides and Related Carboxy Inversion Products in Aqueous Acetone, R.J. Linhardt and B.L. Murr, Tetrahedron Letters, 12, 1007-1010 (1979).
Abstract
The recent report of CINDP during the decomposition of t-butylacetyl m-chlorobenzoyl peroxide, which was interpreted as arising from polarized, rearranged ion pair intermediates, [1] prompts us to report the behavior of ion pairs derived from substituted diphenylacetyl benzoyl peroxides in aqueous acetone. This solvolytic technique allows the study of the polar pathway of peroxide decomposition by comparing product compositions with well-defined energy surfaces established by related solvolytic studies.;
Description
Tetrahedron Letters, 12, 1007-1010; Note : if this item contains full text it may be a preprint, author manuscript, or a Gold OA copy that permits redistribution with a license such as CC BY. The final version is available through the publisher’s platform.
Department
The Linhardt Research Labs.; The Shirley Ann Jackson, Ph.D. Center for Biotechnology and Interdisciplinary Studies (CBIS);
Publisher
Elsevier
Relationships
The Linhardt Research Labs Online Collection; Rensselaer Polytechnic Institute, Troy, NY; https://harc.rpi.edu/;
Access
Rensselaer Open License : further distribution of this electronic version outside of the DSpace@RPI institutional repository is prohibited.; A full text version is available in DSpace@RPI; Open Access;
