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    Mechanism of Decomposition for Diacyl Peroxides and Related Carboxy Inversion Compounds in Aqueous Acetone

    Author
    Linhardt, Robert J.; Murr, B.L.
    ORCID
    https://orcid.org/0000-0003-2219-5833
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    MECHANISM OF DECOMPOSITION FOR DIACYL PEROXIDES AND RELATED CARBOXY INVERSION COMPOUNDS IN AQUEOUS ACETONE.pdf (1.340Mb)
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    Date Issued
    1979
    Subject
    Biology; Chemistry and chemical biology; Chemical and biological engineering; Biomedical engineering
    Degree
    Terms of Use
    In Copyright : this Item is protected by copyright and/or related rights. You are free to use this Item in any way that is permitted by the copyright and related rights legislation that applies to your use. For other uses you need to obtain permission from the rights-holder(s). https://rightsstatements.org/page/InC/1.0/;
    Full Citation
    Mechanism of Decomposition for Diacyl Peroxides and Related Carboxy Inversion Products in Aqueous Acetone, R.J. Linhardt and B.L. Murr, Tetrahedron Letters, 12, 1007-1010 (1979).
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    URI
    https://hdl.handle.net/20.500.13015/5125
    Abstract
    The recent report of CINDP during the decomposition of t-butylacetyl m-chlorobenzoyl peroxide, which was interpreted as arising from polarized, rearranged ion pair intermediates, [1] prompts us to report the behavior of ion pairs derived from substituted diphenylacetyl benzoyl peroxides in aqueous acetone. This solvolytic technique allows the study of the polar pathway of peroxide decomposition by comparing product compositions with well-defined energy surfaces established by related solvolytic studies.;
    Description
    Tetrahedron Letters, 12, 1007-1010; Note : if this item contains full text it may be a preprint, author manuscript, or a Gold OA copy that permits redistribution with a license such as CC BY. The final version is available through the publisher’s platform.
    Department
    The Linhardt Research Labs.; The Shirley Ann Jackson, Ph.D. Center for Biotechnology and Interdisciplinary Studies (CBIS);
    Publisher
    Elsevier
    Relationships
    The Linhardt Research Labs Online Collection; Rensselaer Polytechnic Institute, Troy, NY; https://harc.rpi.edu/;
    Access
    Rensselaer Open License : further distribution of this electronic version outside of the DSpace@RPI institutional repository is prohibited.; A full text version is available in DSpace@RPI; Open Access;
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    • Linhardt Research Labs Papers

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