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dc.contributor.authorYuan, X.
dc.contributor.authorXu, Y.
dc.contributor.authorYou, X.
dc.contributor.authorLinhardt, Robert J.
dc.date2007
dc.date.accessioned2022-06-27T16:14:48Z
dc.date.available2022-06-27T16:14:48Z
dc.date.issued2007
dc.identifier.citationSynthesis of Tin (II) Phosphate Open Frameworks Using Isomers of 1, 2-Diaminocyclohexane as Template, X. Yuan, Y. Xu, X. You, R. J. Linhardt, European Journal of Inorganic Chemistry, 858-864, 2007.
dc.identifier.urihttps://doi.org/10.1002/ejic.200600912
dc.identifier.urihttps://hdl.handle.net/20.500.13015/5767
dc.descriptionEuropean Journal of Inorganic Chemistry, 858-864
dc.descriptionNote : if this item contains full text it may be a preprint, author manuscript, or a Gold OA copy that permits redistribution with a license such as CC BY. The final version is available through the publisher’s platform.
dc.description.abstractA novel layered framework of tin(II) phosphate, [Sn4(PO4)3(OH)]2–·[trans-1,2-C6H10(NH3)2]2+, has been synthesized under hydrothermal conditions with tin(II) oxalate, phosphoric acid and a mixture of trans- and cis-1,2-diaminocyclohexane (1,2-DACH). The compound crystallizes in the monoclinic space group P21/n (No. 14). The channels of the trans-1,2-DACH are occluded by hydrogen bonding in the doubly protonated form, which is leached out from the framework. Reaction using only tran-DACH gives the same compound. For comparison, when cis-DACH is used as template under the same conditions instead of the mixture of trans and cis isomers, the neutral inorganic phosphate framework (Sn3O)2(Sn2O)2(PO4)4 is formed. It crystallizes in the triclinic space group Pequation image (No. 2). These results suggest that trans-1,2-DACH is selectively occluded in the framework [Sn4(PO4)3(OH)]2–·[trans-1,2-C6H10(NH3)2]2+.
dc.description.urihttps://login.libproxy.rpi.edu/login?url=https://doi.org/10.1002/ejic.200600912
dc.languageen_US
dc.language.isoENG
dc.relation.ispartofThe Linhardt Research Labs Online Collection
dc.relation.ispartofRensselaer Polytechnic Institute, Troy, NY
dc.relation.urihttps://harc.rpi.edu/
dc.subjectBiology
dc.subjectChemistry and chemical biology
dc.subjectChemical and biological engineering
dc.subjectBiomedical engineering
dc.titleSynthesis of Tin (II) Phosphate Open Frameworks Using Isomers of 1, 2-Diaminocyclohexane as Template
dc.typeArticle
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dcterms.isVersionOfhttps://doi.org/10.1002/ejic.200600912
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dc.creator.identifierhttps://orcid.org/0000-0003-2219-5833
dc.relation.departmentThe Linhardt Research Labs.
dc.relation.departmentThe Shirley Ann Jackson, Ph.D. Center for Biotechnology and Interdisciplinary Studies (CBIS)


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