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dc.contributor.authorYuan, X.
dc.contributor.authorXu, Y.
dc.contributor.authorYou, X.
dc.contributor.authorLinhardt, Robert J.
dc.identifier.citationSynthesis of Tin (II) Phosphate Open Frameworks Using Isomers of 1, 2-Diaminocyclohexane as Template, X. Yuan, Y. Xu, X. You, R. J. Linhardt, European Journal of Inorganic Chemistry, 858-864, 2007.
dc.descriptionEuropean Journal of Inorganic Chemistry, 858-864
dc.descriptionNote : if this item contains full text it may be a preprint, author manuscript, or a Gold OA copy that permits redistribution with a license such as CC BY. The final version is available through the publisher’s platform.
dc.description.abstractA novel layered framework of tin(II) phosphate, [Sn4(PO4)3(OH)]2–·[trans-1,2-C6H10(NH3)2]2+, has been synthesized under hydrothermal conditions with tin(II) oxalate, phosphoric acid and a mixture of trans- and cis-1,2-diaminocyclohexane (1,2-DACH). The compound crystallizes in the monoclinic space group P21/n (No. 14). The channels of the trans-1,2-DACH are occluded by hydrogen bonding in the doubly protonated form, which is leached out from the framework. Reaction using only tran-DACH gives the same compound. For comparison, when cis-DACH is used as template under the same conditions instead of the mixture of trans and cis isomers, the neutral inorganic phosphate framework (Sn3O)2(Sn2O)2(PO4)4 is formed. It crystallizes in the triclinic space group Pequation image (No. 2). These results suggest that trans-1,2-DACH is selectively occluded in the framework [Sn4(PO4)3(OH)]2–·[trans-1,2-C6H10(NH3)2]2+.
dc.relation.ispartofThe Linhardt Research Labs Online Collection
dc.relation.ispartofRensselaer Polytechnic Institute, Troy, NY
dc.subjectChemistry and chemical biology
dc.subjectChemical and biological engineering
dc.subjectBiomedical engineering
dc.titleSynthesis of Tin (II) Phosphate Open Frameworks Using Isomers of 1, 2-Diaminocyclohexane as Template
dc.rights.holderIn Copyright : this Item is protected by copyright and/or related rights. You are free to use this Item in any way that is permitted by the copyright and related rights legislation that applies to your use. For other uses you need to obtain permission from the rights-holder(s).
dc.relation.departmentThe Linhardt Research Labs.
dc.relation.departmentThe Shirley Ann Jackson, Ph.D. Center for Biotechnology and Interdisciplinary Studies (CBIS)

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