Trifluoroethylsulfonate Protected Monosaccharides in Glycosylation Reactions

Authors
Karst, Nathalie A.
Islam, Tasneem F.
Avci, Fikri Y.
Linhardt, Robert J.
ORCID
https://orcid.org/0000-0003-2219-5833
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Other Contributors
Issue Date
2004-08-16
Keywords
Biology , Chemistry and chemical biology , Chemical and biological engineering , Biomedical engineering
Degree
Terms of Use
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Full Citation
Trifluoroethylsulfonate Protected Monosaccharides in Glycosylation Reactions, N. A. Karst, T. F. Islam, F. Avci, R. J. Linhardt, Tetrahedron Letters, 45, 6433-6437, 2004.
Abstract
A variety of sulfo-protected monosaccharide donors and acceptors were investigated in glycosylation reactions. Trifluoroethylsulfonate (SO3TFE) group was compatible with a wide range of activation conditions commonly used with fluoride, imidate, and sulfide donors. In addition, the influence of a SO3TFE group, at the critical 2-position in glycosyl donor, on the stereoselectivity of the glycosylation reaction was studied.
Description
Tetrahedron Letters, 45, 6433-6437
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Department
The Linhardt Research Labs.
The Shirley Ann Jackson, Ph.D. Center for Biotechnology and Interdisciplinary Studies (CBIS)
Publisher
Relationships
The Linhardt Research Labs Online Collection
Rensselaer Polytechnic Institute, Troy, NY
Tetrahedron Letters
https://harc.rpi.edu/
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https://login.libproxy.rpi.edu/login?url=https://doi.org/10.1016/j.tetlet.2004.06.131