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    Zinc Triflate-Benzoyl Bromide: A Versatile Reagent for the Conversion of Ether into Benzoate Protecting Groups and Ether Glycosides into Glycosyl Bromides

    Author
    Polat, T.; Linhardt, Robert J.
    ORCID
    https://orcid.org/0000-0003-2219-5833
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    Date Issued
    2003-02-14
    Subject
    Biology; Chemistry and chemical biology; Chemical and biological engineering; Biomedical engineering
    Degree
    Terms of Use
    In Copyright : this Item is protected by copyright and/or related rights. You are free to use this Item in any way that is permitted by the copyright and related rights legislation that applies to your use. For other uses you need to obtain permission from the rights-holder(s). https://rightsstatements.org/page/InC/1.0/;
    Full Citation
    Zinc Triflate-Benzoyl Bromide: A Versatile Reagent for the Conversion of Ether into Benzoate Protecting Groups and Ether Glycosides into Glycosyl Bromides, T. Polat, R. J. Linhardt, Carbohydrate Research, 338, 447-449, 2003.
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    URI
    https://doi.org/10.1016/S0008-6215(02)00481-0; https://hdl.handle.net/20.500.13015/5815
    Abstract
    A simple and efficient method is developed for the chemoselective one-pot conversion of ethers (benzyl, TBDMS and acetal) to the corresponding benzoates by zinc triflate-catalyzed deprotection and benzoylation by benzoyl bromide. In the same reaction, methyl or p-methoxyphenyl glycosides are converted into glycosyl bromides that are useful in glycosylation reactions.;
    Description
    Carbohydrate Research, 338, 447-449; Note : if this item contains full text it may be a preprint, author manuscript, or a Gold OA copy that permits redistribution with a license such as CC BY. The final version is available through the publisher’s platform.
    Department
    The Linhardt Research Labs.; The Shirley Ann Jackson, Ph.D. Center for Biotechnology and Interdisciplinary Studies (CBIS);
    Relationships
    The Linhardt Research Labs Online Collection; Rensselaer Polytechnic Institute, Troy, NY; Carbohydrate Research; https://harc.rpi.edu/;
    Access
    https://login.libproxy.rpi.edu/login?url=https://doi.org/10.1016/S0008-6215(02)00481-0;
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