Nanoscale studies of shape memory and superelastic properties of dual-phase shape memory alloys

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Authors
Dar, Rebecca Dorothy
Issue Date
2016-08
Type
Electronic thesis
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Language
ENG
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Materials engineering
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Abstract
Co-Ni-Al is the primary model system selected for experimental studies. In nanoindentation tests using a Berkovich tip (~150 nm radius), enhanced strain recovery, superelastic recovery, and hardness are observed in austenite volume adjacent to its interface with precipitate as compared to other regions tested. A larger radius conospherical tip (~831 nm radius) produces less unrecoverable deformation, thereby enabling a larger portion of material to transform reversibly and is employed in nanoindentation tests in austenite β adjacent to intergranular precipitate, austenite β adjacent to bare grain boundaries, and in austenite β interior. Austenite interfaces adjacent to precipitate have the lowest energy dissipation, the highest hardness, and the highest strain recovery compared to β regions adjacent to bare grain boundaries or β interior. The ductile second phase improves superelasticity by plastically accommodating transformation strain from stress-induced martensitic transformation in its adjacent volume, alleviating stress concentration and relieving constraint on transforming austenite. As a result, a greater portion of austenite transforms reversibly and higher strain recovery is observed in austenite adjacent to the second phase. These results enable design of dual-phase microstructures with enhanced ductility, high recoverable strain, and high hardness for several applications, such as mechanical actuation, damping, and those which apply high loads to materials.
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August 2016
School of Engineering
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Rensselaer Polytechnic Institute, Troy, NY
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