A General Method for the Stereospecific Synthesis of C-glycosidesof Ulosonic Acids by Samarium-Mediated Reductive Dechlorination

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Authors
Polat, T.
Du, Y.
Linhardt, Robert J.
Issue Date
1998
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Article
Language
ENG
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Biology , Chemistry and chemical biology , Chemical and biological engineering , Biomedical engineering
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Abstract
C-glycosylation reactions were performed with the 2-chloroderivatives of NANA, KDN and KDO. C-glycosides were obtainedwhen carbonyl compounds (ketone or sugar aldehyde) were coupled tothe 2-chloro-derivatives of these ulosonic acids under Barbierconditions.
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Synlett, 11, 1195-1196
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A General Method for the Stereospecific Synthesis of C-glycosidesof Ulosonic Acids by Samarium-Mediated Reductive Dechlorination, T. Polat,Y. Du, R.J. Linhardt, Synlett, 11, 1195-1196, 1998.
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