Synthesis of Tin (II) Phosphate Open Frameworks Using Isomers of 1, 2-Diaminocyclohexane as Template
No Thumbnail Available
Authors
Yuan, X.
Xu, Y.
You, X.
Linhardt, Robert J.
Issue Date
2007
Type
Article
Language
ENG
Keywords
Biology , Chemistry and chemical biology , Chemical and biological engineering , Biomedical engineering
Alternative Title
Abstract
A novel layered framework of tin(II) phosphate, [Sn4(PO4)3(OH)]2–·[trans-1,2-C6H10(NH3)2]2+, has been synthesized under hydrothermal conditions with tin(II) oxalate, phosphoric acid and a mixture of trans- and cis-1,2-diaminocyclohexane (1,2-DACH). The compound crystallizes in the monoclinic space group P21/n (No. 14). The channels of the trans-1,2-DACH are occluded by hydrogen bonding in the doubly protonated form, which is leached out from the framework. Reaction using only tran-DACH gives the same compound. For comparison, when cis-DACH is used as template under the same conditions instead of the mixture of trans and cis isomers, the neutral inorganic phosphate framework (Sn3O)2(Sn2O)2(PO4)4 is formed. It crystallizes in the triclinic space group Pequation image (No. 2). These results suggest that trans-1,2-DACH is selectively occluded in the framework [Sn4(PO4)3(OH)]2–·[trans-1,2-C6H10(NH3)2]2+.
Description
European Journal of Inorganic Chemistry, 858-864
Note : if this item contains full text it may be a preprint, author manuscript, or a Gold OA copy that permits redistribution with a license such as CC BY. The final version is available through the publisher’s platform.
Note : if this item contains full text it may be a preprint, author manuscript, or a Gold OA copy that permits redistribution with a license such as CC BY. The final version is available through the publisher’s platform.
Full Citation
Synthesis of Tin (II) Phosphate Open Frameworks Using Isomers of 1, 2-Diaminocyclohexane as Template, X. Yuan, Y. Xu, X. You, R. J. Linhardt, European Journal of Inorganic Chemistry, 858-864, 2007.