HClO4-SiO2 Catalyzed Glycosylation using Sugar Trichloroacetimidates as Glycosyl Donors

Authors
Du, Yuguo
Wei, Guohua
Cheng, Shuihong
Hua, Yuxia
Linhardt, Robert J.
ORCID
https://orcid.org/0000-0003-2219-5833
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Other Contributors
Issue Date
2006-01-16
Keywords
Biology , Chemistry and chemical biology , Chemical and biological engineering , Biomedical engineering
Degree
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Full Citation
HClO4-SiO2 Catalyzed Glycosylation using Sugar Trichloroacetimidates as Glycosyl Donors, Y. Du, G. Wei, S. Cheng, Y. Hua, R. J. Linhardt, Tetrahedron Letters, 47, 307-310, 2006.
Abstract
Silica-supported perchloric acid (HClO4–SiO2) has been used as an efficient promoter, as a replacement of TMSOTf, in various glycosylation reactions using sugar trichloroacetimidates as glycosyl donors. Operational simplicity, economic considerations, high yield, short reaction time and low toxicity were the key features associated with this protocol.
Description
Tetrahedron Letters, 47, 307-310
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Department
The Linhardt Research Labs.
The Shirley Ann Jackson, Ph.D. Center for Biotechnology and Interdisciplinary Studies (CBIS)
Publisher
Relationships
The Linhardt Research Labs Online Collection
Rensselaer Polytechnic Institute, Troy, NY
Tetrahedron Letters
https://harc.rpi.edu/
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