Formation of "methylene" nitrones in some nitrosoarene - olefin reactions

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Authors
Getman, Gerry D.
Issue Date
1975-09
Type
Electronic thesis
Thesis
Language
ENG
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Organic chemistry
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Abstract
On the basis of preliminary kinetic investigations, the mechanism of addition of nitrosobenzene to styrene and similar compounds was advanced as occurring by an initial 2 + 2 cycloaddition of styrene and nitrosobenzene followed by ring opening to a diradical species which reacts with additional nitrosobenzene to form isomeric 2,3,5-triphenyl-1,2,5-oxadiazolidine-N-oxides.
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September 1975
School of Science
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Rensselaer Polytechnic Institute, Troy, NY
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