Mechanism of Decomposition for Diacyl Peroxides and Related Carboxy Inversion Compounds in Aqueous Acetone
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Authors
Linhardt, Robert J.
Murr, B.L.
Issue Date
1979
Type
Language
ENG
Keywords
Biology , Chemistry and chemical biology , Chemical and biological engineering , Biomedical engineering
Alternative Title
Abstract
The recent report of CINDP during the decomposition of t-butylacetyl m-chlorobenzoyl peroxide, which was interpreted as arising from polarized, rearranged ion pair intermediates, [1] prompts us to report the behavior of ion pairs derived from substituted diphenylacetyl benzoyl peroxides in aqueous acetone. This solvolytic technique allows the study of the polar pathway of peroxide decomposition by comparing product compositions with well-defined energy surfaces established by related solvolytic studies.
Description
Tetrahedron Letters, 12, 1007-1010
Note : if this item contains full text it may be a preprint, author manuscript, or a Gold OA copy that permits redistribution with a license such as CC BY. The final version is available through the publisher’s platform.
Note : if this item contains full text it may be a preprint, author manuscript, or a Gold OA copy that permits redistribution with a license such as CC BY. The final version is available through the publisher’s platform.
Full Citation
Mechanism of Decomposition for Diacyl Peroxides and Related Carboxy Inversion Products in Aqueous Acetone, R.J. Linhardt and B.L. Murr, Tetrahedron Letters, 12, 1007-1010 (1979).
Publisher
Elsevier