Stereoselective Total Synthesis of (-)-Cleistenolide
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Authors
Cai, C.
Liu, J.
Du, Y.
Linhardt, Robert J.
Issue Date
2010
Type
Article
Language
ENG
Keywords
Biology , Chemistry and chemical biology , Chemical and biological engineering , Biomedical engineering
Alternative Title
Abstract
A facile stereoselective total synthesis of cleistenolide (1) from the natural chiral template d-arabinose has been achieved in eight steps and 49% overall yield, employing key steps including Wittig olefination, selective 1,3-trans-acetal formation, and modified Yamaguchi esterification.
Description
Journal of Organic Chemistry, in 75, 5754–5756
Note : if this item contains full text it may be a preprint, author manuscript, or a Gold OA copy that permits redistribution with a license such as CC BY. The final version is available through the publisher’s platform.
Note : if this item contains full text it may be a preprint, author manuscript, or a Gold OA copy that permits redistribution with a license such as CC BY. The final version is available through the publisher’s platform.
Full Citation
Stereoselective Total Synthesis of (-)-Cleistenolide, C. Cai, J. Liu, Y. Du, R. J. Linhardt, Journal of Organic Chemistry, in 75, 5754–5756, 2010.
Publisher
American Chemical Society (ACS)