Trifluoroethylsulfonate Protected Monosaccharides in Glycosylation Reactions

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Authors
Karst, Nathalie A.
Islam, Tasneem F.
Avci, Fikri Y.
Linhardt, Robert J.
Issue Date
2004-08-16
Type
Article
Language
ENG
Keywords
Biology , Chemistry and chemical biology , Chemical and biological engineering , Biomedical engineering
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Abstract
A variety of sulfo-protected monosaccharide donors and acceptors were investigated in glycosylation reactions. Trifluoroethylsulfonate (SO3TFE) group was compatible with a wide range of activation conditions commonly used with fluoride, imidate, and sulfide donors. In addition, the influence of a SO3TFE group, at the critical 2-position in glycosyl donor, on the stereoselectivity of the glycosylation reaction was studied.
Description
Tetrahedron Letters, 45, 6433-6437
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Full Citation
Trifluoroethylsulfonate Protected Monosaccharides in Glycosylation Reactions, N. A. Karst, T. F. Islam, F. Avci, R. J. Linhardt, Tetrahedron Letters, 45, 6433-6437, 2004.
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ISSN
404039
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