Trifluoroethylsulfonate Protected Monosaccharides in Glycosylation Reactions
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Authors
Karst, Nathalie A.
Islam, Tasneem F.
Avci, Fikri Y.
Linhardt, Robert J.
Issue Date
2004-08-16
Type
Article
Language
ENG
Keywords
Biology , Chemistry and chemical biology , Chemical and biological engineering , Biomedical engineering
Alternative Title
Abstract
A variety of sulfo-protected monosaccharide donors and acceptors were investigated in glycosylation reactions. Trifluoroethylsulfonate (SO3TFE) group was compatible with a wide range of activation conditions commonly used with fluoride, imidate, and sulfide donors. In addition, the influence of a SO3TFE group, at the critical 2-position in glycosyl donor, on the stereoselectivity of the glycosylation reaction was studied.
Description
Tetrahedron Letters, 45, 6433-6437
Note : if this item contains full text it may be a preprint, author manuscript, or a Gold OA copy that permits redistribution with a license such as CC BY. The final version is available through the publisher’s platform.
Note : if this item contains full text it may be a preprint, author manuscript, or a Gold OA copy that permits redistribution with a license such as CC BY. The final version is available through the publisher’s platform.
Full Citation
Trifluoroethylsulfonate Protected Monosaccharides in Glycosylation Reactions, N. A. Karst, T. F. Islam, F. Avci, R. J. Linhardt, Tetrahedron Letters, 45, 6433-6437, 2004.
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Journal
Volume
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PubMed ID
DOI
ISSN
404039