Zinc Triflate-Benzoyl Bromide: A Versatile Reagent for the Conversion of Ether into Benzoate Protecting Groups and Ether Glycosides into Glycosyl Bromides
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Authors
Polat, T.
Linhardt, Robert J.
Issue Date
2003-02-14
Type
Article
Language
ENG
Keywords
Biology , Chemistry and chemical biology , Chemical and biological engineering , Biomedical engineering
Alternative Title
Abstract
A simple and efficient method is developed for the chemoselective one-pot conversion of ethers (benzyl, TBDMS and acetal) to the corresponding benzoates by zinc triflate-catalyzed deprotection and benzoylation by benzoyl bromide. In the same reaction, methyl or p-methoxyphenyl glycosides are converted into glycosyl bromides that are useful in glycosylation reactions.
Description
Carbohydrate Research, 338, 447-449
Note : if this item contains full text it may be a preprint, author manuscript, or a Gold OA copy that permits redistribution with a license such as CC BY. The final version is available through the publisher’s platform.
Note : if this item contains full text it may be a preprint, author manuscript, or a Gold OA copy that permits redistribution with a license such as CC BY. The final version is available through the publisher’s platform.
Full Citation
Zinc Triflate-Benzoyl Bromide: A Versatile Reagent for the Conversion of Ether into Benzoate Protecting Groups and Ether Glycosides into Glycosyl Bromides, T. Polat, R. J. Linhardt, Carbohydrate Research, 338, 447-449, 2003.
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Terms of Use
Journal
Volume
Issue
PubMed ID
DOI
ISSN
86215